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81.
《Ceramics International》2022,48(1):10-21
Pc-WLEDs are considered to play a spectacular role in future generation light sources in view of their outstanding energy efficiency. In this regard, Eu3+ activated BaY2ZnO5 phosphor was prepared and investigated by XRD, PL and SEM analyses. Rietveld refinement analysis was carried out to confirm the structure of the synthesized phosphor. The prepared phosphor shows an intense red emission around 627 nm under excitation by near UV light. The 5D0-7F2 transition intensity of the prepared phosphor is three times higher compared to the commercial (Y,Gd)BO3:Eu3+ red phosphor. The CIE colour coordinates of BaY2ZnO5:Eu3+ (9mol%) phosphor corresponds to be (0.6169, 0.3742) and it has a high 97.9 % colour purity. The obtained results reveal the utility of BaY2ZnO5:Eu3+ phosphor as an efficient red component in WLEDs, anti-counterfeiting and fingerprint detection applications. 相似文献
82.
《Ceramics International》2022,48(5):6258-6265
Co/W co-doped Na0.5Bi2.5Nb2-x(Co1/3W2/3)xO9 (NBNCW-x) ceramic samples were prepared by the conventional solid state reaction method. The electrical properties and crystal structure of the NBNCW-x ceramic samples were analyzed in detail. The XRD and Rietveld refinement results showed that the samples lattice distortion decreased with the increment of Co/W doping. The XPS results showed that the number of oxygen vacancies in the Na0.5Bi2.5Nb2O9 ceramics could be reduced by the substitution of a small amount of Co/W. The weakened lattice distortion and reduced number of oxygen vacancies of the Na0.5Bi2.5Nb2O9 ceramics synergistically contributed to its improved electrical properties. In particular, the Na0.5Bi2.5Nb1.97(Co1/3W2/3)0.03O9 ceramic exhibited the best performance, and its Tc, d33 and Pr were 780 °C, 24.9 pC/N and 12.6 μC/cm2, respectively. The dielectric loss was only 3.3% at 550 °C. In addition, this ceramic exhibited excellent thermal stability, with the d33 value of the ceramic being 95.2% of its original value when annealed at 750 °C. These properties indicate that the Co/W co-doped Na0.5Bi2.5Nb2O9-based ceramics have potential application in the high-temperature field. 相似文献
83.
84.
长江是我国第一大河流,是世界生物多样性的热点区域,也是我国鱼类多样性最高的河流之一。在介绍长江鱼类主要生态习性生境条件的基础上,分析了导致鱼类多样性下降的主要因素——生境丧失和过度捕捞,并简要总结了目前已采取的保护措施及存在的问题,提出了关于新时期长江鱼类多样性保护的思考与建议:①建立以流域管理机构牵头,相关部门和地方共同组建流域生态保护机制;②有计划开展支流及通江湖泊的生态恢复,使支流的小水电逐步退出,使原本的通江湖泊恢复自然江湖关系;③提高民众环保意识,积极建立全流域禁捕机制和休闲垂钓机制,并让垂钓者成为渔政的管理者和监督者。 相似文献
85.
86.
为减少团聚,提高石墨烯在涂层中的分散性,研究采用纳米分散技术预先制备了石墨烯分散液,再将其分散至环氧树脂中获得石墨烯改性复合涂层。通过对石墨烯含量为 0、0.3%、0.6%的复合涂层进行盐水浸泡、盐雾、阴极剥离实验及电化学性能测试,证明石墨烯的加入显著增强了涂层的防护性能。石墨烯复合涂层在 3.5%盐水中浸泡 1 008 h后,涂层低频阻抗仍大于 106 Ω·cm2比未添加石墨烯的涂层提高了 3个数量级,且盐雾实验 6 000 h后涂层表面仍保持完好;含 0.6%石墨烯,的涂层耐蚀行为劣于石墨烯含量为 0.3%的涂层。 相似文献
87.
为了提高铝颜料在水性涂料中的耐腐蚀性能,以正硅酸乙酯( TEOS)为前驱物,通过溶胶-凝胶反应在铝颜料表面形成了一层致密的二氧化硅包覆薄膜,通过优化固含量、溶剂种类及 TEOS的用量,提高铝颜料的耐碱性。利用扫描电镜、刮板试验、接触角测试、析氢实验进行表征,结果表明:以无水乙醇为溶剂,铝金属颜料固含量为 10%,升温至 50 ℃后,逐滴加入 6 g TEOS,再升温至 80 ℃,该条件下制备的 SiO2膜包覆后的铝颜料具有优异的耐碱性,同时表面性能由疏水性转变成亲水性,对铝颜料起到了很好的保护作用。 相似文献
88.
《Ceramics International》2020,46(3):2910-2914
Porous silicon-bonded silicon carbide (SBSC) ceramics were prepared under argon atmosphere, with silicon as pore former and bonding material, simultaneously, sodium dodecyl benzene sulfonate (SDBS) and ZrO2 as sintering additives, the effects of SDBS and ZrO2 on the porosity, pore size, mechanical, physical and thermal properties and microstructures were investigated. The results suggested that suitable content of SDBS and ZrO2 could not only effectively lower the sintering temperature to 1450 °C due to the sticky flow of molten silicon, but also increase the pore structure and improve the bending strength. The reason for this is that SDBS decomposed into Na2O which reacted with ZrO2 and impurity SiO2, which was the native oxide film on the surface of SiC particles, to form a bonding phase between SiC particles to improve the bending strength; meanwhile, the disappearances of impurity SiO2 would benefit the bond of molten silicon and silicon carbide particles, and silicon melt leaving pores in its original position to increase the pore structure. The optimal apparent porosity, bending strength, average pore size, gas permeance and residual bending strength after thermal shock cycles of SBSC porous ceramic sintered at 1450 °C with 5 wt% SDBS and 6 wt% ZrO2 were 38.33%, 55.4 MPa, 11.3 μm, 106.4 m3/m2·h·kPa and 28.2 MPa, respectively. 相似文献
89.
Kasarapu Venkataramana Chittimadula Madhuri Ch Madhusudan Y.Suresh Reddy G. Bhikshamaiah C.Vishnuvardhan Reddy 《Ceramics International》2018,44(6):6300-6310
In the present study, we investigate the fundamental properties of CeO2 by selecting La3+ (57), and Dy3+ (66) as dopants with optimized average atomic number of 61.5, which lies in between Pm3+ (62) and Sm3+ (62) in accordance with the criteria for optimum doping. A system of co-doped ceria ceramics Ce1–x–yLaxDyyO2-δ ((x, y) = (0.00, 0.00), (0.025, 0.025), (0.05, 0.05), (0.075, 0.075), (0.10, 0.10), (0.00, 0.20) and (0.20, 0.00)) as electrolytes for intermediate temperature solid oxide fuel cells were successfully prepared by a well-known sol-gel auto-combustion route. In order to obtain dense samples, the prepared pellets were sintered in air at 1300 °C for 4 h using conventional furnace and relative densities of all the samples were found to be higher than 95%. Single phase cubic structure, microstructural density and elemental composition analysis of all the samples were studied by powder X-ray diffraction, scanning electron microscope and energy dispersive spectroscopy techniques, respectively. Raman spectroscopy analysis confirmed the formation of concentrated O2-–vacancies in the co-doped ceria system. Impedance spectroscopy measurements revealed the high value of total ionic conductivity and low activation energy for the composition Ce0.85La0.075Dy0.075O2?δ i.e., 2.08 × 10–2 S cm–1 and 0.58 eV, respectively. Linear thermal expansion analyses of all the samples revealed the matched thermal expansion coefficients. Finally, these results recommend that the Ce0.85La0.075Dy0.075O2?δ sample can be useful as a solid electrolyte in IT-SOFC applications. 相似文献
90.
Laccase‐mediated grafting of polyphenols onto cationized cotton fibers to impart UV protection and antioxidant activities 下载免费PDF全文
Suyeon Kim Hyunkyung Lee Juhea Kim Fernando Oliveira Pedro Souto Hyerim Kim Javier Nakamatsu 《应用聚合物科学杂志》2018,135(6)
Enzyme‐mediated in situ functionalization of cotton fibers was studied using laccase. Caffeic acid and morin were used as reactive phenolic substrates for laccase and further employed to the modification of fiber surfaces. Laccase‐mediated oxidation and polymerization reactions of caffeic acid were monitored by ultraviolet–visible spectroscopy. During the wetting process, initial cationization of fiber surfaces using poly(diallyldimethylammonium chloride) followed by enzymatic treatment with phenolic substrates resulted ineffective polymer grafting evidenced by high color stability. Changes of fiber surface properties by polymer grafting, such as morphology and hydrophilicity/hydrophobicity, were tested using scanning electron microscopy and gravimetric absorption tests. An acceptable level of color resistance to washing stress was obtained on caffeic acid treated samples, and a high level of rubbing resistance was obtained on samples treated with both caffeic acid and morin. Regarding the ultraviolet protection test, the cationized and enzymatically functionalized samples showed a very good protection grade (ultraviolet protection factor = 25). Finally, the antioxidant activity test of the modified fibers presented an improvement for radical scavenging potential due to the phenolic compounds incorporated to cotton fibers by laccase‐mediated catalysis. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45801. 相似文献